Determination of the liquid vapour pressure of low-volatility compounds from the Kováts retention index

Determination of Vapor Liquid Equilibriu

Determination of Vapor Liquid Equilibrium from the Kovats Retention Index on Dimethylsilicone using the Wilson Mixing Model

✍ Spieksma, Walter 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 288 KB 👁 2 views

Non-ideal mixing in a dimethylsilicone stationary phase is modeled according to the Wilson activity coefficient. Pure liquid vapor pressures of alkylated compound series are calculated from capillary GLC retention with the functional group heat of solution in a polymer solvent. The new method uses t