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Determination of the isomeric composition of an ionic mixture using collision cross-sections

✍ Scribed by Bo Un Yoon; Myung Soo Kim

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
709 KB
Volume
25
Category
Article
ISSN
1076-5174

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✦ Synopsis

A theory has been developed for the determination of the isomeric composition of an ionic mixture. The probability theory describing the collisionally activated decomposition (CAD) which was developed previously provided a general foundation for the present theory. Quantification was based on the cross-sections for the collisional production of daughter ions as observed in the mass-analysed ion kinetic energy spectrometry (MIKES). Experimental details for the implementation of the theory have also been developed. The method has been applied to the case of C2H,0+' generated from butane-l,Miol, which is known to be a mixture of more than one isomeric structure. The results seem to be far superior to those based on previous methods, as evidenced by the excellent internal consistency.

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