## Abstract It has been found that the interconversion of enantiomers on a chromatographic column during the separation process can be studied by the first‐order kinetic equations derived both for reversible and irreversible reactions in a stationary system if the extent of interconversion is not t
✦ LIBER ✦
Determination of the enantiomerization energy barrier of some 3-hydroxy-1,4-benzodiazepine drugs by supercritical fluid chromatography
✍ Scribed by Peter Oswald; Koen Desmet; Pat Sandra; Jan Krupčı́k; Pavol Májek; Daniel W Armstrong
- Book ID
- 108497330
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 672 KB
- Volume
- 779
- Category
- Article
- ISSN
- 1873-376X
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## Abstract The resonances in the ^13^C NMR spectra of 1,2,5,6‐tetramethyl‐3,4‐dimethylenetricyclo[3.1.0.0^2,6^]hexane and the corresponding enone and dione have been assigned. The rotation energy barriers of the methyl groups have been determined from ^13^C spin‐lattice relaxation time measurement