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Determination of the chiral purity of aminoalcohols by 1H NMR spectroscopy

✍ Scribed by Manfred Michalik; Christian Döbler

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 266 KB
Volume: 46
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)90070-5

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✦ Synopsis

2,2'-Dihydroxy-l,l '-binaphthyl derivatives were used as chiral shift reagents in the chiral recognition of carbocyclic aminoalcohols. The induced chemical shift differences are dependent on the ability of one or both of the OH groups of the shift reagent to coordinate with the substrate molecule for reasons of structure and stereochemistry.

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