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Determination of the average singlet-triplet splitting in biradicals by measurement of the magnetic field dependence of CIDNP [chemically induced dynamic nuclear polarization]

โœ Scribed by Closs, G. L.; Doubleday, C. E.


Book ID
126778143
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
259 KB
Volume
95
Category
Article
ISSN
0002-7863

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Study of chemically induced dynamic nucl
โœ N.E. Polyakov; T.V. Leshina ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 614 KB

The chemically induced dynamic nuclear polarization (CIDNP) method in high and low magnetic fields was applied to the investigation of the photoreduction of p-benzoquinone and duroquinone by aromatic amines (triphenylamine (TPA) and dimethylaniline). CIDNP demonstrates the appearance of both radical