The structure of the title compound, C 14 H 19 N 3 O 9 , has been determined at 100 K. The six-membered ring exhibits a chair conformation, and all non-H substituents are found in equatorial positions.
Determination of the Anomeric Configurations of 2,3,4,6-Tetra-O-Acetyl-D-Mannopyranosyl Azide
β Scribed by Cosgrove, Kelly L.; Bernhardt, Paul V.; Ross, Benjamin P.; McGeary, Ross P.
- Book ID
- 115497714
- Publisher
- Commonwealth Scientific and Industrial Research Organisation Publishing
- Year
- 2006
- Tongue
- English
- Weight
- 256 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0004-9425
- DOI
- 10.1071/ch06157
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Synthesis and Structural Studies of Anomeric 2,3,4,6-Tetra-O-acetyl-5-thio-D-glucopyranosyl Azides. -Two alternative routes for the synthesis of both anomers of the title compound (II)/(III) are given. Both methods are comparable in yield but the route starting from glucopyranosyl bromide (I) is pr
## Crystals of the tetrasaccharide, (2,3,4,6-tetra-0acetyl-fi-D-ghxopyranosyl~-(1 + 3)-[2,3,4,6-tetra-O-acetyI+LD-gIucopyranosyI-(1 --t 6)]-(2,4-di-0-acetyl-g\_D-glucopyranosyl)-1 --) 3)-1,2,4,6-tetrad-acetyl$?-n-ghicopyranose, belong to tge monoclinic system, space group P2,, with a = 12.709(4),