Determination of the aluminium coordination in aluminium-oxygen compounds by solid-state high-resolution 27AI NMR
✍ Scribed by D. Müller; W. Gessner; H.J. Behrens; G. Scheler
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 285 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Hgh
-resolutton 27Al NhlR spectra of polycrystalhne alumrnntes have been studled at 70 4 hfHz hlaglc-angle spummg was used to reduce quadrupole effects and dlpolar mtenctlon. The isotropic *'Al chenuul shrfts depend mamly on the AI-O coordmatlon For Al-O tetrahedra stufts of 55 to 80 ppm were measured III contrast to those of Al-0 octahedra at 0 ppm
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