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Determination of the aluminium coordination in aluminium-oxygen compounds by solid-state high-resolution 27AI NMR

✍ Scribed by D. Müller; W. Gessner; H.J. Behrens; G. Scheler


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
285 KB
Volume
79
Category
Article
ISSN
0009-2614

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✦ Synopsis


Hgh

-resolutton 27Al NhlR spectra of polycrystalhne alumrnntes have been studled at 70 4 hfHz hlaglc-angle spummg was used to reduce quadrupole effects and dlpolar mtenctlon. The isotropic *'Al chenuul shrfts depend mamly on the AI-O coordmatlon For Al-O tetrahedra stufts of 55 to 80 ppm were measured III contrast to those of Al-0 octahedra at 0 ppm


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