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Determination of the absorption cross section for methyl at 216.36 nm and the absolute rate constant for methyl radical recombination over the temperature range 296-577 K

โœ Scribed by Macpherson, Martyn T.; Pilling, Michael J.; Smith, Martin J. C.


Book ID
126311409
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
838 KB
Volume
89
Category
Article
ISSN
0022-3654

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โœ Martyn T. Macpherson; Michael J. Pilling; Martin J.C. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 346 KB

I%c rate conswnt for methyl rzdic;ll recombination has been measured over the rempcrature range 296-577 K and at pressures bcl\vcrn 5 and 500 Torr win: laser 5~11 photolysis. coupled with absorption spectroscopy at 216.36 nm. Analysis 01' lhC f~ll-ol'f curves gives k, = (1.78 2 0.18) x IO-" rsp( 151

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