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Determination of the Absolute Configurations of γ-Rubromycin and Related Spiro Compounds by Quantum Chemical CD Calculations

✍ Scribed by Gerhard Bringmann; Jürgen Kraus; Ullrich Schmitt; Carsten Puder; Axel Zeeck


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
393 KB
Volume
2000
Category
Article
ISSN
1434-193X

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Determination of absolute configurations
✍ Jan Sandström 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 343 KB 👁 1 views

The usefulness and limitations of the CNDO/S method for calculations of rotational strengths of inherently chiral chromophores are illustrated with examples from bridged biphenyls. The more empirical Schellman matrix method is employed to calculate CD spectra of compounds containing two chirally dis