✦ LIBER ✦

Determination of the absolute configuration of stelliferasterol and strongylosterol - two marine sterols with “extended” side chains

✍ Scribed by Norbert Theobald; Carl Djerassi

Book ID: 104246250
Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 247 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95226-8

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✦ Synopsis

The unusual side chains encountered in recent years1 among marine sterols may ultimately prove to be of considerable significance in determining the role of sterols, other than cholesterol, in membrane function.

2 Of particular interest in that regard are the uniquely marine sterols with "extended" side chains and their possible biosynthetic origin. Aplysterol (1) and its 24-28 de-hydra analog have until recently been the only sterols3 with ".extended" side chains, i.e. with an

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