𝔖 Bobbio Scriptorium
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Determination of the absolute configuration of natural products

✍ Scribed by KONG, Ling-Yi; WANG, Peng


Book ID
121402377
Publisher
Elsevier
Year
2013
Tongue
Chinese
Weight
761 KB
Volume
11
Category
Article
ISSN
1875-5364

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Synthesis of the enantiomers of sclerosp
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Both the enantiomers of sclerosporin 1 and sclerosporal 2 were synthesized from (-)carvone. (4R, 9R, lOR)-(+)-Sclerosporin and (4R, 9R, lOR)-(-)-sclerosporal were identified as natural enantiomers by bio-assay and by the CD-spectral comparison. Sclerosporin 1, the main sporogenic substance isolated