The importance of 10 Be in different applications of accelerator mass spectrometry (AMS) is well-known. In this context the half-life of 10 Be has a crucial impact, and an accurate and precise determination of the half-life is a prerequisite for many of the applications of 10 Be in cosmic-ray and ea
Determination of the 10Be half-life by multicollector ICP-MS and liquid scintillation counting
✍ Scribed by Jérôme Chmeleff; Friedhelm von Blanckenburg; Karsten Kossert; Dieter Jakob
- Book ID
- 103863635
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 430 KB
- Volume
- 268
- Category
- Article
- ISSN
- 0168-583X
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✦ Synopsis
A new method was designed and used for determining the half-life of the isotope 10 Be. The method is based on (1) accurate 10 Be/ 9 Be measurements of 9 Be-spiked solutions of a 10 Be-rich master solution using multicollector ICP mass spectrometry (MC-ICP-MS) and (2) liquid scintillation counting (LSC) using the CIEMAT/NIST method for determining the activity concentrations of the solutions whose 10 Be concentrations were determined by mass spectrometry. Important requirements for the success of this approach (a) was the previous coating of glass ampoules filled for counting experiments with 9 Be, thereby reducing the risk of the adsorptive loss of 10 Be; (b) the removal of Boron from solutions to be measured by MC-ICP-MS by cation chromatography without the introduction of mass fractionation and (c) the accurate determination of the mass bias of 10 Be/ 9 Be measurements by ICP-MS which are always affected by the space-charge effect. The mass bias factor was determined to be 1.1862 ± 0.071 for 10 Be/ 9 Be from careful fitting and error propagation of ratios of measured Li, B, Si, Cr, Fe, Cu, Sr, Nd, Hf, Tl and U standard solutions of known composition under the same measurement conditions. Employing this factor, an absolute 10 Be/ 9 Be ratio of 1.464 ± 0.014 was determined for a first dilution of the 10 Be-rich master solution. This solution is now available as an absolute Be ratio standard in AMS measurements. Finally, a half-life of (1.386 ± 0.016) My (standard uncertainty) was calculated. This value is much more precise than previous estimates and was derived from a fully independent set of experiments. In a parallel, fully independent study using the same master solution, Korschinek et al. [35] have determined a half-life of (1.388 ± 0.018) My. The combined half-life and uncertainty amounts to (1.387 ± 0.012) My. We suggest the use of this value in nuclear studies and in studies that make use of cosmogenic 10 Be in environmental and geologic samples.
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