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Determination of S−H Bond Strengths in Dimolybdenum Tetrasulfide Complexes

✍ Scribed by Appel, Aaron M.; Lee, Suh-Jane; Franz, James A.; DuBois, Daniel L.; Rakowski DuBois, M.; Twamley, Brendan


Book ID
126205372
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
394 KB
Volume
28
Category
Article
ISSN
0276-7333

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The dlfference between the metal-metal 6 and TT orbItal lonlzation energws for the complexes M~(OZCCF&, M2(02CCH3)4, M2(CaHsf.+\_ and Mz(hlHP)1, (where M = Cr or MO and H{MHP)= 6-methyl-2-hydrouypyrtdme) mcreases, wtthm each series. as the metal-metal bond length decreases. The vanahon m the metal-m