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Determination of reaction rate constants for alkylation of 4-(p-Nitrobenzyl) pyridine by different alkylating agents

โœ Scribed by Walles, S.A.Solveig


Book ID
121998067
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
525 KB
Volume
5
Category
Article
ISSN
0378-4274

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Rate constants for the reactions of alky
โœ J. A. Hawari; P. S. Engel; D. Griller ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 220 KB ๐Ÿ‘ 1 views

An electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from l,4-cyclohexadiene. Rate constants for the reaction were ca. 104-105 M-' s-' at 300 K and activation energies 5-7 kcal mol-'. For the stabilized radicals, ally1 and benzyl, t