The two stereochemically distinct two-bond carbon-13-hydrogen coupling constants J(13C-CH), for cr-chloro~tyrene-a-'~C have been shown to be of similar magnitude but opposite sign (-6.3 and 1 5 . 6 Hz). A simple additivity relationship which adequately reproduces all the reported J(13C-CH) values fo
Determination of proton-proton coupling constants in 13C-labeled molecules
β Scribed by C Griesinger; U Eggenberger
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 561 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
A new method is shown to determine C,C spin coupling constants in C 2 symmetric molecules by using proton detection with gradient selected 2QHMBC. It is shown that the pulse sequence proposed distinguishes between symmetric and antisymmetric eigenfunctions of the AAXX spin system.
## Abstract Analysis of the noise decoupled ^13^C spectra of doubly ^13^C labelled compounds where the two labelled carbons are identical, makes the determination of reltive signs of ^13^Cο£Ώ^13^C coupling constants possible in a very simple way. The involved carbon form AA'X or AA'B spin systems.