Determination of optical sums from the small angle electron impact spectra of argon
โ Scribed by H.F. Wellenstein; R.A. Bonham
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 414 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
A method for obtaining optical sums directly from high energy (25 keV) electron impact spectra in the forward direction is suggested. The electron energy loss spectrum of argon at an energy resolution of +-600 meV was obtained for energy losses from zero to 50 eV and 200 to 300 eV at an energy resolution of 5 eV averaged over an angular range of -+5 ร 10 -4 radians. The data were corrected for finite detector size, gas and electron beam spatial distributions to obtain an estimate of the zero angle scattering spectrum. A hydrogenic contribution was assumed for the 3p, 3s continuum for energy loss greater than 50 eV and for the 2p continuum for energy loss greater than 280 eV. Various moments of the spectrum were computed and related to optical sums by use of the measured experimental moments of the energy distribution of the incident beam and the scale factor needed to place the data on an absolute scale. The scale factor was obtained by use of the Thomas-Reiche-Kuhn sum rule. The results are in excellent agreement with previous estimates of the various sum rules and the present approach shows promise for providing useful data for a large number of atomic and molecular targets.
๐ SIMILAR VOLUMES
Encrzy 10s'~ spectra for argon by 30 eV electron impact have been measured f'or srzttering anglas from 1.5" to 70'. TWO new loss peaks are observed in the spectra; cnc correspondin, n ta the 3d (13.86 eV) excitation, the other corresponding to the 3d3 fL 3.97 eV) excitqtion. The reIr?tivc cross sect
The optical absorption of small mass selected Ag. clusters (n = 57, 9, 11) embedded in solid Ar has been measured. Strong absorption has been found between 3 and 4.5 eV. The absorption spectra show l-3 major peaks depending on the cluster size. The width of these peaks is considerably smaller than c
The mean resonance energy (do> =R.fwwa(o) do/\_fu(o) dw calculated from the optical absorption spectra ofAg, in solid Ar shows strong variations as a function of cluster size, giving maxima at n =8,18 and 34. This behavior is discussed in terms of the electronic shell model. Static dipole polarizabi