Determination of microamounts of zirconium(IV) and titanium(IV) with preliminary TLC separation
✍ Scribed by Lidija B. Pfendt; Slavoljub Petrović; Vasilije Ž. Pašajlić
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 455 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0026-265X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Water-soluble phthalocyaninato zirconium(IV) and hafnium(IV) complexes have been synthesized for the first time. An increased solubility in comparison to PcZrCl ~2~ and PcHfCl ~2~ was caused by the introduction of gallic, 1,8-dihydroxynaphthalene-3,6-disulfonic (chromotropic), and 5-sulfosalicylic a
## Abstract Treatment of titanyl sulfate in about 60 mM sulfuric acid with NaL~OEt~ (L~OEt~^−^=[(η^5^‐C~5~H~5~)Co{P(O)(OEt)~2~}~3~]^−^) afforded the μ‐sulfato complex [(L~OEt~Ti)~2~(μ‐O)~2~(μ‐SO~4~)] (2). In more concentrated sulfuric acid (>1 M), the same reaction yielded the di‐μ‐sulfato complex