Determination of Mercury by Anodic Stripping Voltammetry with a Gold Nanoparticle-Modified Glassy Carbon Electrode

✍ Scribed by Ornella Abollino; Agnese Giacomino; Mery Malandrino; Giuseppina Piscionieri; Edoardo Mentasti

• Publisher: John Wiley and Sons
• Year: 2008
• Tongue: English
• Weight: 284 KB
• Volume: 20
• Category: Article
• ISSN: 1040-0397
• DOI: 10.1002/elan.200704044

✦ Synopsis

Abstract

The aim of this work is the development of a procedure for the determination of aqueous Hg(II) by anodic stripping voltammetry at a gold nanoparticle‐modified glassy carbon electrode (AuNPs‐GCE). The signal of aqueous Hg(II) was measured in the square wave mode; the effect of potential scan parameters, deposition potential and deposition time on the analytical signal was examined. The supporting electrolyte was 0.06 M HCl. The repeatability, the linearity, the accuracy, the detection limit of the procedure and the interferences of other cations and of anions were evaluated. The performance of the AuNPs‐GCE was compared with those of a solid (SGE) and a film (FGE) gold electrode: the AuNPs‐GCE showed to provide lower detection limits and higher repeatability. The renewable surface permits to eliminate memory effects, to maintain a stable baseline and response, and to avoid frequent mechanical cleaning steps. The applicability of the AuNPs‐GCE for Hg(II) determination in drinking waters, sediments and pharmaceuticals was demonstrated.