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Determination of keto–enol equilibrium constants and the kinetic study of the nitrosation reaction of β-dicarbonyl compounds

✍ Scribed by Iglesias, Emilia


Book ID
120178287
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
588 KB
Volume
3
Category
Article
ISSN
1472-779X

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Substituent effects in keto-enol tautome
✍ M. Bassetti; G. Cerichelli; B. Floris 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 437 KB

The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h