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Determination of Hydrogen Peroxide in Rainwater by Using a Polyaniline Film and Platinum Particles Co-Modified Carbon Fiber Microelectrode

✍ Scribed by Yu Wang; Junhua Huang; Chunguang Zhang; Jingbao Wei; Xingyao Zhou


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
62 KB
Volume
10
Category
Article
ISSN
1040-0397

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✦ Synopsis


Four types of carbon fiber microelctrodes modified with polyaniline (PAn) and platinum particles (Pt) were fabricated to determine H 2 O 2 at þ 0.60 V (vs. SCE). The sensitivity, stability and selectivity of different electrodes were compared. The electrode modified with a sandwich film of PAn-Pt-PAn offered the best result. The linear range was 4.0 × 10 ¹7 -2.4 × 10 ¹4 M with a detection limit of 1.0 × 10 ¹7 M. The relative standard deviation (RSD) for 10 mM H 2 O 2 was 1.9 % (n ¼7). The electrode was used to determine the H 2 O 2 in the rainwater.