The Kinetics of Substitution Reactions o
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Marjaana Mikola; Karel D. Klika; Jorma Arpalahti
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Article
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2000
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John Wiley and Sons
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English
β 261 KB
π 2 views
In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking