Determination of force constants for the spherically symmetric potential functions
โ Scribed by M.P. Saksena; J.M. Gandhi; V.P.S. Nain
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 283 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A new method employing simultaneously two equilibrium properties, viz., the second virial and Joule-Thomson coefficients, has been developed to determine the force constants involved in spherically symmetric potential functions. The method is tested for nitrogen for which adequate experimental data e,xist.
๐ SIMILAR VOLUMES
A method is given for computing the fourth virial coefficient D(fl for a pairwise additive spherically symmetric interaction potential. Taking one of the four interacting particles as origin and using the appropriate co-ordinate transformations in the usual way the ninefold integrals defining D(fl a
Explicit formulas are given for the characters of symmetric and antisymmetric powers of an arbitrary representation up to the sixth, and a general method for obtaining the higher ones is described. The results allow, among others, the determination of nonvanishing higher force constants in symmetric