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Determination of chlorine and dissolved oxygen in waters and of ascorbic acid in pharmaceuticals by iodimetric potentiometric titration using a plasticized poly(vinyl chloride) membrane electrode

✍ Scribed by Concepción Sánchez-Pedreño; Joaquín A. Ortuño; J. Hernández


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
592 KB
Volume
333
Category
Article
ISSN
0003-2670

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✦ Synopsis


The response to triiodide of an electrode based on a membrane containing poly(viny1 chloride) and 2nitrophenyl octyl ether as plasticizer in a 1:2 (w/w) ratio is studied. The electrode is suitable for the automatic potentiometric titration of triiodide in the concentration range lo-' -10e3 mall-' with thiosulphate.

The electrode has been satisfactorily applied to the determination of chlorine and dissolved oxygen in tap waters and that of ascorbic acid in pharmaceuticals.

Possible explanations for the response of the membrane to triiodide are included.