Determination of chemical shift anisotropy without a reference and of direct and indirect spin-spin couplings between heteronuclei
β Scribed by C.L. Khetrapal; A.C. Kunwar
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 185 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0009-2614
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We present a simple method for extracting interference effects between chemical shift anisotropy (CSA) and dipolar coupling from spin relaxation measurements in macromolecules, and we apply this method to extracting cross-correlation rates involving interference of amide 15N CSA and 15N-1H dipolar c
## Abstract A simple procedure is presented for the determination of the asymmetry parameter of the electric field gradient, the quadrupole coupling constant, the secondβorder quadrupolar shift and the isotropic chemical shift of quadrupolar nuclei with halfβinteger spin directly from the experimen