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Determination of Carboxylic Acid Anhydrides in Presence of Their Acids

โœ Scribed by Siggia, Sidney; Hanna, J Gordon


Book ID
126130867
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
297 KB
Volume
23
Category
Article
ISSN
0003-2700

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The reactivity of the aziridinium cation towards the hydroxyl group of alcohols and phenols makes possible a simple synthesis of 2-alkoxyethylamines 111. If the reaction is carried out with a-hydroxy esters ( I ) and aziridinium tetrafluoroborate (2), one obtains first the salts (3) and then, by lo