High-performance liquid chromatography (HPLC) in combination with atmospheric pressure chemical ionization mass spectrometry (APcI-MS) was applied to the determination of the phenolic fraction found in methanolic extracts of sunflower seeds (mainly chlorogenic acid and derived compounds). These extr
Determination of caffeic and chlorogenic acids and their derivatives in different sunflower seeds
✍ Scribed by Pedrosa, Mercedes M; Muzquiz, Mercedes; Garc�a-Vallejo, Concepci�n; Burbano, Carmen; Cuadrado, Carmen; Ayet, Gemma; Robredo, Luz M
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 102 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0022-5142
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✦ Synopsis
Five different genotypes (Tesoro, Marko, Clip, Vyp-70 and Nanta) of sun¯ower seeds were studied and the phenolic compositions of their kernel and hull were characterised by HPLC and MS techniques. The main phenolic compounds present in both the kernel and hull are chlorogenic acid, caffeic acid and two caffeoylquinic derivatives. Both derivatives were characterised by partial alkaline hydrolysis and LC/MS. The four phenolic compounds present in the kernel ranged from 94.6% (genotype Clip) to 99.3% (genotype Marko) of the total phenolic compounds of the whole seed. Therefore the dehulling of the seed scarcely improves its nutritional value.
📜 SIMILAR VOLUMES
Homologous series of dihydroxamic acids [HONHCO(CH 2 n CONHOH with n D 0, 1, 2, 3, 4 and 6] were prepared and trimethysilylated [1(n) and 2(n)]. The solution NMR spectra ( 1 H, 13 C, 15 N) of 1(n) show that the hydroxamic end groups assume Z-Z and Z-E combinations of conformers. An exception is oxal