Determination of Binding Constants of Hydrogen-Bonded Complexes by ITC, NMR CIS, and NMR Diffusion Experiments
✍ Scribed by Christiane Dethlefs; Jens Eckelmann; Hauke Kobarg; Thomas Weyrich; Stefan Brammer; Christian Näther; Ulrich Lüning
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 266 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
It is demonstrated that by two-dimensional spin-diffusion powder NMR spectroscopy it is possible to determine accurately relative interaction-tensor orientations. This technique is applied to the determination of the asymmetry of the potential for the proton exchange across the hydrogen bonds in cry
## Abstract NMR chemical shift titration has been widely used as a method for the determination of stability constants. Systems involving metal‐ligand complexation have been investigated using a number of methodologies. There are significant differences in the values reported for stability constant