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Determination of Alkyl Sulfides and Disulfides

โœ Scribed by Siggia, Sidney.; Edsberg, R. L.

Book ID
121378003
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
253 KB
Volume
20
Category
Article
ISSN
0003-2700

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Rate constants for the reactions of tert-butoxy radicals (generated by the thermal decomposition of di-tert-butylperoxyoxalate) with several sulfur containing compounds have been measured a t 310 K in benzene. Hexanethiol ( k = 6.5 x lO'M-'s-') reacts considerably faster than alkyl sulfides and disu