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Determination of addition rates of thiyl radicals to vinyl monomers by means of flash photolysis. 8. Polar effect in addition rates of substituted benzenethiyl radicals to .alpha.-methylstyrene determined by flash photolysis

โœ Scribed by Ito, Osamu; Matsuda, Minoru


Book ID
126913372
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
513 KB
Volume
47
Category
Article
ISSN
0022-3263

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Absolute rate constants for the addition of the highly nucleophilic 2-hydroxy-2-propyl radical to eight fast-reacting 1and 1,l-disubstituted alkenes in MeOH at room temperature have been determined by laser flash photolysis. Also the absorption spectra of the 2-hydroxy-2-propyl and the benzylic and