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Determination of Absolute Configuration Using Concerted ab Initio DFT Calculations of Electronic Circular Dichroism and Optical Rotation: Bicyclo[3.3.1]nonane Diones

✍ Scribed by Stephens, P. J.; McCann, D. M.; Butkus, E.; Stončius, S.; Cheeseman, J. R.; Frisch, M. J.


Book ID
111672461
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
140 KB
Volume
69
Category
Article
ISSN
0022-3263

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Determination of the absolute configurat
✍ Eugenius Butkus; Sigitas Stončius; Albinas Žilinskas 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB 👁 1 views

## Abstract A study of the enantiomers of bicyclo[3.3.1]nonane‐2,7‐dione, a chiral molecule containing two carbonyl chromophores, was performed. Enantiomers of this structure were obtained by HPLC resolution and the (+)‐(1R,5S)‐enantiomer by enantiospecific synthesis from(+)‐(1S,5S)‐bicyclo[3.3.1]n