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Detection of vacant tetrahedral sites in thiospinels by 57Fe Mössbauer spectroscopy and diffuse reflectance

✍ Scribed by M Womes; F Py; M.L.Elidrissi Moubtassim; J.C Jumas; J Olivier-Fourcade; F Aubertin; U Gonser


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
674 KB
Volume
55
Category
Article
ISSN
0022-3697

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Site Preference of Fe and V in PbFexV6−x
✍ A.C. Dhaussy; O. Mentre; F. Abraham; Y. Calage 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 258 KB

The PbFe x V 6؊x O 11 series adopting the R block structural type were investigated by both powder neutron di4raction and MoK ssbauer spectroscopy in order to quantify a Fe 3؉ cation occupancy in available crystallographic sites. Four samples with formal x ratio of 1, 1.21, 1.6, and 1.75 were invest