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Detection of the syn conformer of allyl alcohol by free jet microwave spectroscopy

✍ Scribed by Sonia Melandri; Paolo G. Favero; Walther Caminati

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
389 KB
Volume
223
Category
Article
ISSN
0009-2614

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✦ Synopsis

The rotational spectrum of ally1 alcohol has been investigated with a free jet millimeter wave spectrometer in the frequency range 60-78 GHz. The spectra of the normal and OD monodeuterated species of the syn conformer have been assigned. They are characterized by the tunneling splittings due to the hydroxyl group internal rotation. These vibrational splittings amount to 14168.15 and 937.66 MHz for the normal and deuterated species, respectively.

πŸ“œ SIMILAR VOLUMES

Assignment of a Third Conformer of N-Met
Assignment of a Third Conformer of N-Methyl Ethylenediamine by Free-Jet Absorption Microwave Spectroscopy
✍ W. Caminati; P.G. Favero; A. Millemaggi; L.B. Favero; S. Melandri πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 317 KB

The microwave spectrum of a third conformer (T2t) of \(N\)-methyl ethylenediamine has been assigned using a free-jet millimeter-wave spectrometer in the frequency range \(60-78 \mathrm{GHz}\). T2t has an intermediate energy with respect to those of two conformers ( \(T 1\) and \(T 2 g\) ) previously