Detection of the ground state FO radical in the gas phase
โ Scribed by M.A.A. Clyne; R.T. Watson
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 300 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The infrared laser absorption spectrum of the PO 2 free radical has been detected in the reaction of oxygen atoms with white phosphorus. Over 300 lines of the u 3 fundamental band of the 2A 1 ground state have been measured and assigned between 1300 and 1345 cm-1. Rotational, centrifugal distortion
Fourier transform infrared spectroscopy was used to identify CH2FOOH and HC(O)F as products of the gas-phase reaction of CHIFOz radicals with HOs radicals. At 700 Torr and 295 + 2 K, branching ratios for the CHrFOOH forming channel, k,,/k, =0.29 f 0.08 and the HC(O)F channel, klb/kl =0.71 f 0.11 wer