✦ LIBER ✦

Detection of oxygen (3P) atoms in pulsed vacuum UV photolysis of NO and its application to O atom reactions

✍ Scribed by F. Stuhl; H. Niki

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 513 KB
Volume: 7
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)80286-x

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✦ Synopsis

Formation of 0 atoms by the pulsed vacuum W photolysis of NO has been observed using the chemilumfnescent reaction 0 f NO(+M) 0 + NO + He -NO2 + He and 0 + -NO&M). With this method, absolute rate constants for the reactions NO T -+ 02 + NO were determined directly to be 6.7 x LO-32cm6 moIecule-%sec-1 and 4.4 x lo-12 cm3 mo ecule*I set-1 by monitoring the 0 atom deeaye in the presence of

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