Redox Chemistry in the Reaction of Oxova
β
Hua-Fen Hsu; Chia-Ling Su; Neeruganti O. Gopal; Chi-Chin Wu; Wei-Cheng Chu; Yi-F
π
Article
π
2006
π
John Wiley and Sons
π
English
β 158 KB
## Abstract The reactions of V^V^O(Oβ__i__Pr)~3~ with [PS3β²]H~3~ and [PS3]H~3~ {[PS3β²]H~3~ = P(C~6~H~3~β5βMeβ2βSH)~3~, [PS3]H~3~ = P(C~6~H~4~β2βSH)~3~} led to the formation of [V^IV^(L)] [L = P2S4β² (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3β² or PS3 ligands by a disulf