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Detection of nitrosofuran anion radicals in the electrochemical reduction of 5-nitrofuran. EPR investigations and quantum-chemical calculations

โœ Scribed by T. S. Isichenko; L. M. Baider; V. B. Luzhkov

Publisher
Springer US
Year
1989
Tongue
English
Weight
468 KB
Volume
25
Category
Article
ISSN
0009-3122

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Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics