Detection of deep traps for gas molecules in the diffusion processes in low-molecular glasses

✍ Scribed by S.V. Vasenkov; V.A. Tolkatchev; N.M. Bazhin

• Publisher: Elsevier Science
• Year: 1993
• Tongue: English
• Weight: 363 KB
• Volume: 207
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(93)85010-l

✦ Synopsis

The kinetics of the diffusion-controlled radical oxidation in glassy alcohol matrices of n-butanol-d10 and isopcntanol has been studied at various concentrations of oxygen and nitrogen in the samples. The influences of matrix annealing and gas concentrations on the kinetics have been analyzed. A conclusion on the existence of deep traps for gas molecules in n-butanol-dlo and isoamyl alcohol is drawn.