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Detection of Anisotropic Hyperfine Transitions in Zero Magnetic Field Using Field-Cycling Techniques

✍ Scribed by G Sturm; D Kilian; A Lötz; J Voitländer

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
86 KB
Volume
142
Category
Article
ISSN
1090-7807

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✦ Synopsis

For the first time, we describe the detection of hyperfine transitions in zero magnetic field using field-cycling techniques and pulsed EPR spectroscopy. The sample investigated was coal, which shows an anisotropic electron spin-13 C hyperfine interaction.

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Recently several investigators reported opti-aZ detection of ESR transitions in phosphoresent triplet states of various molecules [l-3]. he experiments were done by sweeping the magetic field at fixed microwave frequency. In con-;ast with the normal ESR detection method. the Jsorption of microwave p