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Detection of a second triplet state in thiophosgene by electron-impact spectroscopy

โœ Scribed by Wayne M. Flicker; Oren A. Mosher; Aron Kuppermann

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
277 KB
Volume
57
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The ebctron-tipact energy-Zoss spedrum of thiophosgexxe was iwesf&ted at incident energies of 25 eV and 40 eV a.d scatXe&g mgk~ fhm 0" ?o SO". fn these spectra we obserw a preti0usIy unreported triplet state at 3.1 f 0.1 eV w&&b is tentathely assigned as the 1 3Al @r, IT*) state. This state may play a role io Wiamokcuk radbtionkss transitions in this molecule. * mds work was supposted in part by a conts2ct OZY-76-O?-767) from the Department of Energy. Report Code: CALT-?67P4-166.

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Triplet states in the dissociative excit
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โœ C.A.F. Johnson; S.D. Kelly; J.E. Parker ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 419 KB

The electron-impact excltahon of water ha been remves~.~gated over the energy range 9-180 eV Energy-dependent pressure effects have been observed It IS suggested that these are due to production of one or more mplet states of water which udergo coU~s~onally ass~s~cd prtissoclatlon Threshold energxs