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Detection of 2,5-dimethylene-2,5-dihydrothiophene and thiophenoradialene

✍ Scribed by Norbert Münzel; Karl Kesper; Armin Schweig; Harald Specht

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
232 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reactive species alene have been detected for the first generally applicable method for generating heterocyclic

Below we report on the generation and spectroscopic detection of the hitherto unknown reactive intermediates 2,5-dimethylene-2,5_dihydrothiophene

1 and tetramethylenetetrahydrothiophene (thiophenoradialene) 2 using the Variable Temperature Photoelectron Spectroscopy (VTPES) and Flash V acuum Pyrolysis Matrix Isolation Technique (FVP MIT).' \ 4

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