A detailed kinetic mechanism capable of modeling aromatic ring breakdown in benzene flames has been developed through reaction path and systematic sensitivity analyses. The model incorporates benzene oxidation and pyrolysis steps, a C 5 chemistry submechanism and some novel features such as lineariz
Detailed reduction of reaction mechanisms for flame modeling
β Scribed by Hai Wang; Michael Frenklach
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 406 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0010-2180
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β¦ Synopsis
A method for reduction of detailed chemical reaction mechanisms, introduced earlier for ignition systems, was extended to laminar premixed flames. The reduction is based on testing the reaction and reaction-enthalpy rates of the "full" reaction mechanism using a zero-dimensional model with a flame temperature profile as a constraint. The technique is demonstrated with numerical tests performed on the mechanism of methane combustion.
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