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Detailed potential energy surfaces for carbonium ion rearrangements: C3H7O+

✍ Scribed by Bowen, Richard D.; Kalman, John R.; Williams, Dudley H.

Book ID
127033643
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
372 KB
Volume
99
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Potential energy profiles for unimolecul
Potential energy profiles for unimolecular reactions of organic ions: [C3H8N]+ and [C3H7O]+
✍ Richard D. Bowen; Dudley H. Williams; G. Hvistendahl; John R. Kalman πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 895 KB

The unimolecular decompositions of two isomers of [C&N]+, CH3CH2CH=NH2 and CH3CHzh=CH,, are dis-ed in terms of the potential energy profile over which reaction may be considered to occur. The energy needed to promote slow (metastable) dissociations of either ion is found to be less than that require