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Detailed Kinetics and Mechanism of the Oxidation of Thiocyanate Ion (SCN – ) by Peroxomonosulfate Ion (HSO 5– ). Formation and Subsequent Oxidation of Hypothiocyanite Ion (OSCN – )

✍ Scribed by Kalmár, József; Lente, Gábor; Fábián, István

Book ID
120335141
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
806 KB
Volume
52
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of acetylacetone by permanganate ion
✍ Miklós Jáky; János Szammer; Edit Simon-Trompler 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

## Abstract The kinetics and mechanism of permanganate ion oxidation of acetylacetone (Acac) was studied in acidic and alkaline media. The rate constants for keto, enol, and enolate anions were determined and discussed. Delocalization of the π‐electrons of the double bond by conjugation results in