This paper presents a semi-detailed and lumped kinetic model of poly(chloroprene) thermal degradation. This is the extension of a previous paper in which a polyvinylchloride (PVC) pyrolysis mechanism was presented. The mechanism of 38 species and pseudocomponents (molecules and radicals) involved in
Detailed kinetic modeling of the thermal degradation of vinyl polymers
โ Scribed by Alessandro Marongiu; Tiziano Faravelli; Eliseo Ranzi
- Book ID
- 108155125
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 885 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0165-2370
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A new kinetic model was developed to describe the thermal degradation behavior of polymers. The model was applied to predict the degradation of poly(methyl methacrylate) (PMMA) blended with propyl ester phosphazene (FR). The results showed that the thermal degradation mechanism of pure PMMA was domi
## Abstract The degradation of a high polymer is the process of breakdown by various agencies of the long chain molecules. In the case of vinyl polymers, (the degradation reaction, though not so important commercially as the polymerization process,) may be utilized in various ways; for instance, (a