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Detailed hydrocarbon analysis of gasoline by GC-MS (SI-PIONA)

✍ Scribed by Teng, Siu T. ;Williams, Anthony D. ;Urdal, Kjell


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
565 KB
Volume
17
Category
Article
ISSN
0935-6304

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✦ Synopsis


Abstract

A gas chromatographic – mass spectrometric (GC‐MS) method has been developed for detailed analysis of the hydrocarbon content of gasoline. The method is equipped with special software and includes the analysis of oxygenated compounds in a single run. The technique utilizes three basic components: the separating power of high resolution capillary gas chromatography, a mass spectrometer with a controllable ion source and ion fragmentation ratios, and unique software for data handling and preparation of reports. The C~4~ to C~12~ range of hydrocarbons in gasoline is covered by the method. A sample of unleaded gasoline from a gas station was analyzed without sample preparation. The results are discussed.


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## Abstract This paper describes the use of multidimensional capillary gas chromatography for analysis of individual components in a C~9~C~10~ aromatic hydrocarbon pyrolysis distillate containing substantial amounts of aromatic olefins. By coupling this GC‐GC system on‐line to a mass spectrometer