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Detailed copolymerization propagation kinetics of homogeneous phase VDF–HFP copolymerization in supercritical CO2

✍ Scribed by Siegmann, Rebekka; Drache, Marco; Beuermann, Sabine

Book ID
121453789
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
395 KB
Volume
159
Category
Article
ISSN
0022-1139

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## Abstract A kinetic model is developed for the heterogeneous free‐radical copolymerization of vinylidene fluoride and hexafluoropropylene in supercritical CO~2~. The model accounts for polymerization in both the dispersed (polymer‐rich) phase and in the continuous (polymer‐free) supercritical pha