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Desymmetrizing Hydroformylation of Dialkenylcarbinols with the Aid of a Planar-Chiral, Catalyst-Directing Group

✍ Scribed by Bernhard Breit; Daniel Breuninger


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
277 KB
Volume
2005
Category
Article
ISSN
1434-193X

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Desymmetrizing Hydroformylation of Diall
✍ Bernhard Breit; Daniel Breuninger πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 244 KB

## Abstract The desymmetrizing hydroformylation of diallylcarbinols has been achieved by employing a planar‐chiral, substrate‐bound catalyst‐directing group β€” the __ortho__‐(diphenylphosphanyl)ferrocenylcarbonyl group (__o__‐DPPF). The method allows the simultaneous construction of two stereogenic