Desulfurizative cyclopropanation of 2-(1-alkenyl)-1,3-dithianes and substituted 1,3-bis(phenylthio)-1-propenes with titanocene-olefin complexes
β Scribed by Yasuo Horikawa; Tadahiro Nomura; Mikako Watanabe; Ichiro Miura; Tooru Fujiwara; Takeshi Takeda
- Book ID
- 103411116
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 341 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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The desulfurization of 1,3-bis(phenylthio)alk-l-enes with the low valent titanium species CP2Ti[P(OEt)3]2 and subsequent reaction with tert-alkyl chlorides gave the terminal olefins regioselectively. The similar reactions also took place when 1~,'/-unsaturated thioacetals were treated successively w
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