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Desulfurization reaction of cis-1,2-diphenyl-3-aryl-1,4,2-diazaphospholidin-5-thione-2-oxides utilizing an Ag+−H2O or ROH system

✍ Scribed by Jia Zhou; Ruyu Chen

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
205 KB
Volume
9
Category
Article
ISSN
1042-7163

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✦ Synopsis

A desulfurization reaction of the title compounds, as cyclic substrates, utilizing an Ag ‫ם‬ -H 2 O or ROH system, is described in this article. The diastereoisomerism of ring-opening products and the possible reaction mechanism are also discussed. The molecular structure of ␣-(3-phenylureido)-␣-(2,4dichlorophenyl)methylphenylphosphinic acid (4a) was determined by X-ray diffraction.

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