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Desulfurisation and ring opening of cyclic trithiocarbonates at a dimolybdenum centre

โœ Scribed by Adams, Harry; Bancroft, Matthew N.; Morris, Michael J.


Book ID
125487377
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
107 KB
Volume
15
Category
Article
ISSN
1359-7345

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โœ Yuxia Liu; Charles U. Pittman Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 304 KB ๐Ÿ‘ 2 views

Three unsubstituted cyclic ketene acetals (CKAs), 2-methylene-1,3-dioxolane, 1a, 2-methylene-1,3-dioxane, 2a, and 2-methylene-1,3-dioxepane, 3a, undergo exclusive 1,2addition polymerization at low temperatures, and only poly(CKAs) are obtained. At higher temperatures, ring-opening polymerization (RO